Issue 26, 2012
From the journal:

Chemical Communications

Enantioselective carbonyl–ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors†

Xiao Liu,ab   Shiyang Bai,ab   Yan Yang,ab   Bo Li,a   Bing Xiao,a   Can Lia  and  Qihua Yang*a  

* Corresponding authors

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China
E-mail: yangqh@dicp.ac.cn
Fax: +86-411-84694447

b Graduate School of the Chinese Academy of Sciences, Beijing 100049, China

Abstract

An asymmetric multicomponent catalyst, BINOLate/titanium, successfully encapsulated in the nanocages of mesoporous silicas exhibits much higher activity than the homogeneous counterpart in quasi solvent-free enantioselective carbonyl–ene reaction, owing to the confinement effect of the nanoreactor.

Graphical abstract: Enantioselective carbonyl–ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

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Article information

DOI
https://doi.org/10.1039/C2CC17950D
Article type
Communication
Submitted
20 Dec 2011
Accepted
30 Jan 2012
First published
01 Feb 2012

Chem. Commun., 2012,48, 3191-3193

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Enantioselective carbonyl–ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

X. Liu, S. Bai, Y. Yang, B. Li, B. Xiao, C. Li and Q. Yang, Chem. Commun., 2012, 48, 3191 DOI: 10.1039/C2CC17950D

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