Issue 25, 2012
From the journal:

Chemical Communications

Practical synthesis of aromatic nitrilesviagallium-catalysed electrophilic cyanation of aromatic C–H bonds†

Kazuhiro Okamoto,a   Masahito Watanabe,a   Masahito Murai,a   Ryo Hatanoa  and  Kouichi Ohe*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Nishikyo-ku, Japan
E-mail: ohe@scl.kyoto-u.ac.jp

Abstract

A gallium-catalysed, direct cyanation reaction of aromatic and heteroaromatic C–H bonds with cyanogen bromide was developed as a practical synthetic method for the preparation of aromatic nitriles.

Graphical abstract: Practical synthesis of aromatic nitrilesviagallium-catalysed electrophilic cyanation of aromatic C–H bonds

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Article information

DOI
https://doi.org/10.1039/C2CC18008A
Article type
Communication
Submitted
22 Dec 2011
Accepted
02 Feb 2012
First published
03 Feb 2012

Chem. Commun., 2012,48, 3127-3129

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Practical synthesis of aromatic nitrilesviagallium-catalysed electrophilic cyanation of aromatic C–H bonds

K. Okamoto, M. Watanabe, M. Murai, R. Hatano and K. Ohe, Chem. Commun., 2012, 48, 3127 DOI: 10.1039/C2CC18008A

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