Issue 25, 2012
From the journal:

Chemical Communications

trans-1,2-Diaminocyclohexane mesoporous silica for asymmetric catalysis: enhancement of chirality through confinement space by the plug effect†

Eun-Young Jeong,a   Cheang-Rae Lim,a   Hailian Jina  and  Sang-Eon Park*a  

* Corresponding authors

a Lab. of Nano-Green Catalysis and Nano Center for Fine Chemical Fusion Technology, Dept of Chemistry, Inha University, In-Cheon, Korea
E-mail: separk@inha.ac.kr
Fax: +82-872-8670
Tel: +82-860-7675

Abstract

trans-1,2-Diaminocyclohexane functionalized mesoporous silica was applied as an ideal catalyst for asymmetric Michael addition of various nitroalkane derivatives. Short channels and plugs in the pore structure offered chiral enhancement in Michael addition.

Graphical abstract: trans-1,2-Diaminocyclohexane mesoporous silica for asymmetric catalysis: enhancement of chirality through confinement space by the plug effect

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Article information

DOI
https://doi.org/10.1039/C2CC18095B
Article type
Communication
Submitted
27 Dec 2011
Accepted
27 Jan 2012
First published
31 Jan 2012

Chem. Commun., 2012,48, 3079-3081

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trans-1,2-Diaminocyclohexane mesoporous silica for asymmetric catalysis: enhancement of chirality through confinement space by the plug effect

E. Jeong, C. Lim, H. Jin and S. Park, Chem. Commun., 2012, 48, 3079 DOI: 10.1039/C2CC18095B

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