Issue 31, 2012
From the journal:

Chemical Communications

Helicity inversion from left- to right-handed square planar Pd(ii) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism†

Hiroyuki Miyake,*a   Masashi Ueda,a   Saori Murota,a   Hideki Sugimoto‡a  and  Hiroshi Tsukubeab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: miyake@sci.osaka-cu.ac.jp

b CREST (JST), Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

Abstract

A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions.

Graphical abstract: Helicity inversion from left- to right-handed square planar Pd(ii) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC18154A
Article type
Communication
Submitted
30 Dec 2011
Accepted
21 Feb 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 3721-3723

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Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

H. Miyake, M. Ueda, S. Murota, H. Sugimoto and H. Tsukube, Chem. Commun., 2012, 48, 3721 DOI: 10.1039/C2CC18154A

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