Issue 33, 2012
From the journal:

Chemical Communications

A homochiral diamond framework constructed from Fe(iii) and Mn(ii) oxo-clusters supported by Sb(iii) tartrate scaffolds†

Qiang Gao,a   Xiqu Wanga  and  Allan J. Jacobson*a  

* Corresponding authors

a Department of Chemistry, University of Houston, Houston, USA
E-mail: ajjacob@uh.edu

Abstract

A homochiral diamond framework was obtained by using a secondary building unit (SBU) comprising an oxo-cluster containing 4Fe(III) and 3Mn(II) ions supported by Sb3O tartrate scaffolds. A fully protonated tetratopic cation, tetrakis(4-pyridyloxymethylene)methane (TPOM), acts as a template to arrange the clusters on a diamond lattice.

Graphical abstract: A homochiral diamond framework constructed from Fe(iii) and Mn(ii) oxo-clusters supported by Sb(iii) tartrate scaffolds

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Article information

DOI
https://doi.org/10.1039/C2CC18174F
Article type
Communication
Submitted
30 Dec 2011
Accepted
25 Feb 2012
First published
27 Feb 2012

Chem. Commun., 2012,48, 3990-3992

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A homochiral diamond framework constructed from Fe(III) and Mn(II) oxo-clusters supported by Sb(III) tartrate scaffolds

Q. Gao, X. Wang and A. J. Jacobson, Chem. Commun., 2012, 48, 3990 DOI: 10.1039/C2CC18174F

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