Issue 27, 2012
From the journal:

Chemical Communications

Electrode kinetics at carbon electrodes and the density of electronic states†

Rita Nissim,a   Christopher Batchelor-McAuley,a   Martin C. Henstridgea  and  Richard G. Compton*a  

* Corresponding authors

a Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford OX1 3QZ, UK
E-mail: richard.compton@chem.ox.ac.uk
Fax: +44 (0)1865 275410
Tel: +44 (0)1865 275413

Abstract

Marcus–Hush theory relates the rate of electron transfer to the density of electronic states of the electrode material. Through use of a carbon microelectrode—for which the density of states is expected to vary as a function of potential—this predication is validated for graphitic materials by measurement of a variety of outer-sphere redox systems.

Graphical abstract: Electrode kinetics at carbon electrodes and the density of electronic states

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Article information

DOI
https://doi.org/10.1039/C2CC30165B
Article type
Communication
Submitted
09 Jan 2012
Accepted
03 Feb 2012
First published
03 Feb 2012

Chem. Commun., 2012,48, 3294-3296

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Electrode kinetics at carbon electrodes and the density of electronic states

R. Nissim, C. Batchelor-McAuley, M. C. Henstridge and R. G. Compton, Chem. Commun., 2012, 48, 3294 DOI: 10.1039/C2CC30165B

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