PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response

Chuan-Fu Sun; Chun-Li Hu; Jiang-Gao Mao

doi:10.1039/C2CC30326D

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PbPt(IO₃)₆(H₂O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response†

Chuan-Fu Sun,^a Chun-Li Hu^a and Jiang-Gao Mao*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: mjg@fjirsm.ac.cn

Abstract

A new polar material containing two types of stereoactive lone-pairs has been synthesized. The unique parallel alignment of the stereoactive lone-pairs on Pb²⁺ cations and the synergistic effect of two types of stereoactive lone-pairs on I⁵⁺ and Pb²⁺ cations make it exhibit a very large second-harmonic generation response of about 8 × KDP (KH₂PO₄).

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Article information

DOI: https://doi.org/10.1039/C2CC30326D
Article type: Communication
Submitted: 15 Jan 2012
Accepted: 05 Mar 2012
First published: 05 Mar 2012

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Chem. Commun., 2012,48, 4220-4222

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PbPt(IO₃)₆(H₂O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response

C. Sun, C. Hu and J. Mao, Chem. Commun., 2012, 48, 4220 DOI: 10.1039/C2CC30326D

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