Issue 33, 2012
From the journal:

Chemical Communications

Indium(iii) catalysed substrate selective hydrothiolation of terminal alkynes†

Rupam Sarma,a   Nimmakuri Rajesha  and  Dipak Prajapati*a  

* Corresponding authors

a Medicinal Chemistry Division, CSIR-North-East Institute of Science & Technology, Assam, India
E-mail: dr_dprajapati2003@yahoo.co.uk
Fax: +91 376 2370011

Abstract

In(OTf)3 is reported as the first catalyst having the ability to selectively catalyse both Markovnikov and anti-Markovnikov hydrothiolation of terminal alkynes under identical reaction conditions depending upon the nature of the thiol employed.

Graphical abstract: Indium(iii) catalysed substrate selective hydrothiolation of terminal alkynes

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Article information

DOI
https://doi.org/10.1039/C2CC30350G
Article type
Communication
Submitted
16 Jan 2012
Accepted
02 Mar 2012
First published
02 Mar 2012

Chem. Commun., 2012,48, 4014-4016

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Indium(III) catalysed substrate selective hydrothiolation of terminal alkynes

R. Sarma, N. Rajesh and D. Prajapati, Chem. Commun., 2012, 48, 4014 DOI: 10.1039/C2CC30350G

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