Issue 41, 2012
From the journal:

Chemical Communications

Toward aceneporphyrinoids: synthesis and transformations of palladium(ii) meso-anthriporphyrin†‡

Bartosz Szyszko,a   Lechosław Latos-Grażyński*a  and  Ludmiła Szterenberga  

* Corresponding authors

a Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50-383 Wrocław, Poland
E-mail: lechoslaw.latos-grazynski@chem.uni.wroc.pl
Web: http://llg.chem.uni.wroc.pl/
Fax: +48 71-328-2348

Abstract

meso-Anthriporphyrin is a carbaporphyrinoid with an anthracene ring embedded in the tripyrrolic framework. The coordination of palladium(II) results in a specific intramacrocyclic metal(II)–η2-CC interaction which facilitates the cleavage to palladium(II) acyclic oligopyrrole with the appended anthracene moiety.

Graphical abstract: Toward aceneporphyrinoids: synthesis and transformations of palladium(ii) meso-anthriporphyrin

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Article information

DOI
https://doi.org/10.1039/C2CC30362K
Article type
Communication
Submitted
16 Jan 2012
Accepted
20 Mar 2012
First published
20 Mar 2012

Chem. Commun., 2012,48, 5004-5006

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Toward aceneporphyrinoids: synthesis and transformations of palladium(II) meso-anthriporphyrin

B. Szyszko, L. Latos-Grażyński and L. Szterenberg, Chem. Commun., 2012, 48, 5004 DOI: 10.1039/C2CC30362K

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