Issue 35, 2012
From the journal:

Chemical Communications

Spin state dependence of electrical conductivity of spin crossover materials†

Aurelian Rotaru,ab   Il'ya A. Gural'skiy,ac   Gábor Molnár,a   Lionel Salmon,a   Philippe Demontd  and  Azzedine Bousseksou*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, CNRS UPR-8241 and Université de Toulouse, UPS, INP, F-31077 Toulouse, France
E-mail: azzedine.bousseksou@lcc-toulouse.fr

b Faculty of Electrical Engineering and Computer Science, Stefan cel Mare University, 13 Str. Universitatii, Suceava 720229, Romania

c Department of Chemistry, National Taras Shevchenko University, 62 Vladimirska str, 01601 Kiev, Ukraine

d LPP-CIRIMAT, CNRS & Université de Toulouse III, 118 Route de Narbonne, 31062 Toulouse, France

Abstract

We studied the spin state dependence of the electrical conductivity of the spin crossover compound [Fe(Htrz)2(trz)](BF4) (Htrz = 1H-1,2,4-triazole) by means of dc electrical measurements. The low spin state is characterized by higher conductance and lower thermal activation energy of the conductivity, when compared to the high spin state.

Graphical abstract: Spin state dependence of electrical conductivity of spin crossover materials

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Article information

DOI
https://doi.org/10.1039/C2CC30528C
Article type
Communication
Submitted
23 Jan 2012
Accepted
07 Mar 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 4163-4165

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Spin state dependence of electrical conductivity of spin crossover materials

A. Rotaru, I. A. Gural'skiy, G. Molnár, L. Salmon, P. Demont and A. Bousseksou, Chem. Commun., 2012, 48, 4163 DOI: 10.1039/C2CC30528C

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