Issue 36, 2012
From the journal:

Chemical Communications

Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions†

Bernd Schmidt*a  and  Nelli Elizarova  

* Corresponding authors

a Universitaet Potsdam, Institut fuer Chemie, Organische Synthesechemie, Karl-Liebknecht-Straße 24-25, D-14476 Potsdam-Golm, Germany
E-mail: bernd.schmidt@uni-potsdam.de

Abstract

A sequence of acetamide directed oxidative Heck reaction and deacetylation–diazotation–Heck coupling allows the traceless removal of the acetamide group and its dual exploitation as a catalyst directing group and a leaving group.

Graphical abstract: Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions

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Article information

DOI
https://doi.org/10.1039/C2CC30752A
Article type
Communication
Submitted
02 Feb 2012
Accepted
14 Mar 2012
First published
15 Mar 2012

Chem. Commun., 2012,48, 4350-4352

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Selective arene functionalization through sequential oxidative and non-oxidative Heck reactions

B. Schmidt and N. Elizarov, Chem. Commun., 2012, 48, 4350 DOI: 10.1039/C2CC30752A

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