Issue 38, 2012
From the journal:

Chemical Communications

Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent–organic frameworks†

Yi Du,*a   Kanmi Mao,a   Preeti Kamakoti,a   Peter Ravikovitch,a   Charanjit Paur,a   Stephen Cundy,a   Quanchang Lia  and  David Calabro*a  

* Corresponding authors

a ExxonMobil Research and Engineering Company, Corporate Strategic Research Laboratory, 1545 Route 22 East, Annandale, USA
E-mail: yi.du@exxonmobil.com, dccalabro@exxonmobil.com
Fax: 001 908 730 3355

Abstract

Pyridine-modified COF-10 exhibits enhanced stability in humid air relative to un-modified COF-10. Solid state NMR and computational studies were used to probe the nature of pyridine interactions with the framework. We propose two models for pyridine–framework interactions with different stabilities.

Graphical abstract: Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent–organic frameworks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC30781B
Article type
Communication
Submitted
03 Feb 2012
Accepted
14 Mar 2012
First published
21 Mar 2012

Chem. Commun., 2012,48, 4606-4608

Permissions

Request permissions

Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent–organic frameworks

Y. Du, K. Mao, P. Kamakoti, P. Ravikovitch, C. Paur, S. Cundy, Q. Li and D. Calabro, Chem. Commun., 2012, 48, 4606 DOI: 10.1039/C2CC30781B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements