Issue 39, 2012
From the journal:

Chemical Communications

Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers†

Francisco J. Muñoz Lara,a   Ana B. Gaspar,a   Daniel Aravena,b   Eliseo Ruiz,b   M. Carmen Muñoz,c   Masaaki Ohba,d   Ryo Ohtani,e   Susumu Kitagawaef  and  José A. Real*a  

* Corresponding authors

a Institut de Ciència Molecular/Departament de Química Inorgánica, Universitat de València, Edifici d'Instituts de Paterna, Carrer Catedràtic José Beltrán Martínez 2, València, Spain
E-mail: jose.a.real@uv.es

b Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, Barcelona 08028, Spain

c Departament de Física Aplicada, Universitat Politècnica de València, Camí de Vera s/n, 46022 València, Spain

d Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan

e Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

f Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)4]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.

Graphical abstract: Enhanced bistability by guest inclusion in Fe(ii) spin crossover porous coordination polymers

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Article information

DOI
https://doi.org/10.1039/C2CC31048A
Article type
Communication
Submitted
13 Feb 2012
Accepted
19 Mar 2012
First published
20 Mar 2012

Chem. Commun., 2012,48, 4686-4688

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Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers

F. J. Muñoz Lara, A. B. Gaspar, D. Aravena, E. Ruiz, M. C. Muñoz, M. Ohba, R. Ohtani, S. Kitagawa and J. A. Real, Chem. Commun., 2012, 48, 4686 DOI: 10.1039/C2CC31048A

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