Issue 41, 2012
From the journal:

Chemical Communications

Interior aliphatic C–H bond activation on iron(ii) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation†‡

Wei-Min Chingab  and  Chen-Hsiung Hung*a  

* Corresponding authors

a Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan
E-mail: chhung@chem.sinica.edu.tw
Fax: +886-2-27831237
Tel: +886-2-27898570

b Department of Chemistry, National Taiwan Normal University, Taipei, Taiwan

Abstract

Iron oxidation, in conjunction with NO coordination, achieved a C–H bond activation to convert [FeII(HCTPPCH3)Br] into [Fe(HCTPPCH2)(NO)](BF4) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a π-accepting ligand to assist the C–H bond activation.

Graphical abstract: Interior aliphatic C–H bond activation on iron(ii) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation

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Article information

DOI
https://doi.org/10.1039/C2CC31053H
Article type
Communication
Submitted
13 Feb 2012
Accepted
22 Mar 2012
First published
22 Mar 2012

Chem. Commun., 2012,48, 4989-4991

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Interior aliphatic C–H bond activation on iron(II) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation

W. Ching and C. Hung, Chem. Commun., 2012, 48, 4989 DOI: 10.1039/C2CC31053H

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