Heteropolyanions, [GaNb18O54]15− and [AlNb18O54]15−, have been synthesized and characterized. These represent the first examples of introducing group III elements into the heteropolyniobate family; achieved via compatible alkaline aqueous chemistry of group IIIA monomers and Nb-polyoxoanions. The open structure of the polyniobate results in expanded coordination of the tetrahedral Ga in aqueous medium.
Y. Hou, T. M. Alam, M. A. Rodriguez and M. Nyman, Chem. Commun., 2012, 48, 6004 DOI: 10.1039/C2CC31284K
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