Issue 46, 2012
From the journal:

Chemical Communications

A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition†

Chou-Fu Sheu,a   Che-Hsiu Shih,bc   Kunihisa Sugimoto,cd   Bing-Ming Cheng,e   Masaki Takatabcd  and  Yu Wang*a  

* Corresponding authors

a Department of Chemistry, National Taiwan University, Taipei, Taiwan, R.O.C
E-mail: wangyu@ntu.edu.tw
Tel: +886-2-33661654

b Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561, Japan

c RIKEN SPring-8 center, Sayo, Hyogo 679-5148, Japan

d Japan Synchrotron Radiation Research Institute, Sayo, Hyogo 679-5148, Japan

e National Synchrotron Radiation Research Center, Hsinchu, Taiwan, R.O.C

Abstract

In addition to the generally observed LIESST phenomenon, polymorph D of trans-[FeII(abpt)2(NCS)2] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

Graphical abstract: A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

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Article information

DOI
https://doi.org/10.1039/C2CC31326J
Article type
Communication
Submitted
22 Feb 2012
Accepted
20 Mar 2012
First published
20 Mar 2012

Chem. Commun., 2012,48, 5715-5717

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A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

C. Sheu, C. Shih, K. Sugimoto, B. Cheng, M. Takata and Y. Wang, Chem. Commun., 2012, 48, 5715 DOI: 10.1039/C2CC31326J

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