Issue 53, 2012
From the journal:

Chemical Communications

Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies†‡

Maxim N. Sokolov,*ab   Sergey A. Adonin,ab   Pavel A. Abramov,ab   Dmitry A. Mainichev,a   Nina F. Zakharchuka  and  Vladimir P. Fedinab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Prosp. Lavrentieva 3, Novosibirsk, Russia
E-mail: caesar@niic.nsc.ru
Fax: +7 383-330-94-89
Tel: +7 383-316-58-45

b Novosibirsk State University, 630090, ul.Pirogova 2, Novosibirsk, Russia.

Abstract

A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na12[(Rh4(μ3–O)2(H2O)2)(H2W9O33)2]·38H2O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by 183W NMR data; 1 is active in electrocatalytic water oxidation.

Graphical abstract: Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC31692G
Article type
Communication
Submitted
07 Mar 2012
Accepted
12 May 2012
First published
15 May 2012

Chem. Commun., 2012,48, 6666-6668

Permissions

Request permissions

Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

M. N. Sokolov, S. A. Adonin, P. A. Abramov, D. A. Mainichev, N. F. Zakharchuk and V. P. Fedin, Chem. Commun., 2012, 48, 6666 DOI: 10.1039/C2CC31692G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements