Issue 53, 2012
From the journal:

Chemical Communications

Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and l-lactide†

Yuan Wanga  and  Haiyan Ma*a  

* Corresponding authors

a Shanghai Key Laboratory of Functional Materials Chemistry and Laboratory of Organometallic Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai, P. R. China
E-mail: haiyanma@ecust.edu.cn
Fax: +86 21 64253519
Tel: +86 21 64253519

Abstract

By combining the influence of excess alcohol, temperature and monomer-to-initiator ratios in the feed, dinuclear salan aluminum complexes LRAl2Me4 exhibited a high degree of control towards the copolymerization of L-LA and ε-CL, producing blocky, gradient, tapered and random copolymers.

Graphical abstract: Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and l-lactide

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Article information

DOI
https://doi.org/10.1039/C2CC31716H
Article type
Communication
Submitted
08 Mar 2012
Accepted
11 May 2012
First published
11 May 2012

Chem. Commun., 2012,48, 6729-6731

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Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and L-lactide

Y. Wang and H. Ma, Chem. Commun., 2012, 48, 6729 DOI: 10.1039/C2CC31716H

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