Issue 47, 2012
From the journal:

Chemical Communications

Ni-catalyzed construction of C–P bonds from electron-deficient phenolsvia the in situaryl C–O activation by PyBroP†

Yu-Long Zhao,ab   Guo-Jie Wub  and  Fu-She Han*ac  

* Corresponding authors

a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China
E-mail: fshan@ciac.jl.cn
Tel: +86-431-8526-2936

b Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

c State Key Laboratory of Fine Chemicals, Dalian 116024, China

Abstract

The C–P bond forming reaction using electron-deficient phenol substrates was considerably challenging. Herein, we present a new protocol that allows for one-pot construction of C–P bonds via the cross-coupling of phenols and phosphine oxide or phosphite in the presence of a nickel catalyst.

Graphical abstract: Ni-catalyzed construction of C–P bonds from electron-deficient phenols via the in situ aryl C–O activation by PyBroP

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Article information

DOI
https://doi.org/10.1039/C2CC31718D
Article type
Communication
Submitted
08 Mar 2012
Accepted
18 Apr 2012
First published
18 Apr 2012

Chem. Commun., 2012,48, 5868-5870

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Ni-catalyzed construction of C–P bonds from electron-deficient phenols via the in situ aryl C–O activation by PyBroP

Y. Zhao, G. Wu and F. Han, Chem. Commun., 2012, 48, 5868 DOI: 10.1039/C2CC31718D

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