Issue 44, 2012
From the journal:

Chemical Communications

Deca-heterosubstituted corannulenes†

Alla Pogoreltsev,‡a   Ephrath Solel,‡a   Doron Pappo*b  and  Ehud Keinan*ac  

* Corresponding authors

a Schulich Faculty of Chemistry, Technion — Israel Institute of Technology, Technion City, Haifa 32000, Israel
E-mail: keinan@technion.ac.il
Fax: +972-4-8293913
Tel: +972-4-8293913

b Department of Chemistry, Ben-Gurion University, Beer-Sheva 84105, Israel
E-mail: pappod@bgu.ac.il
Fax: +972-8-6428693
Tel: +972-8-6428692

c Department of Molecular Biology and the Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, USA

Abstract

The Cu(I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.

Graphical abstract: Deca-heterosubstituted corannulenes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC31801F
Article type
Communication
Submitted
11 Mar 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Chem. Commun., 2012,48, 5425-5427

Permissions

Request permissions

Deca-heterosubstituted corannulenes

A. Pogoreltsev, E. Solel, D. Pappo and E. Keinan, Chem. Commun., 2012, 48, 5425 DOI: 10.1039/C2CC31801F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements