Issue 49, 2012
From the journal:

Chemical Communications

Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes†

Takahiro Sawano,a   Keiyu Ou,a   Takahiro Nishimura*a  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp, thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988
Tel: +81 75 753 3987

Abstract

Asymmetric addition of silylacetylenes to meso-oxa- and azabenzonorbornadienes took place in the presence of a cobalt/QuinoxP* catalyst to give the addition products in good yields with high enantioselectivity.

Graphical abstract: Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

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Article information

DOI
https://doi.org/10.1039/C2CC31880F
Article type
Communication
Submitted
14 Mar 2012
Accepted
25 Apr 2012
First published
25 Apr 2012

Chem. Commun., 2012,48, 6106-6108

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Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

T. Sawano, K. Ou, T. Nishimura and T. Hayashi, Chem. Commun., 2012, 48, 6106 DOI: 10.1039/C2CC31880F

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