Issue 45, 2012

Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

Abstract

A new class of chiral sulfoxide–Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide–Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to 98% yield and 96% ee).

Graphical abstract: Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

Supplementary files

Article information

Article type
Communication
Submitted
15 Mar 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Chem. Commun., 2012,48, 5596-5598

Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

H. Cheng, L. Lu, T. Wang, J. Chen and W. Xiao, Chem. Commun., 2012, 48, 5596 DOI: 10.1039/C2CC31907A

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