Issue 53, 2012
From the journal:

Chemical Communications

Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H2 activation†

Zi-Jian Yao,a   Xian-Kuan Huoa  and  Guo-Xin Jin*ab  

* Corresponding authors

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, P. R. China
E-mail: gxjin@fudan.edu.cn
Fax: +86-21-65641740

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, P. R. China

Abstract

Several novel zwitterionic half-sandwich complexes and pseudocloso metallacarboranes based on 1,2-(PPh2)2-1,2-C2B10H10 were successfully prepared, and further study proved that some of them can activate H2 to form the metal hydride complexes Cp*M(H)(7,8-(PPh2)2-7,8-C2B9H10) (M = Rh, Ir).

Graphical abstract: Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H2 activation

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Article information

DOI
https://doi.org/10.1039/C2CC32036C
Article type
Communication
Submitted
20 Mar 2012
Accepted
08 May 2012
First published
09 May 2012

Chem. Commun., 2012,48, 6714-6716

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Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H2 activation

Z. Yao, X. Huo and G. Jin, Chem. Commun., 2012, 48, 6714 DOI: 10.1039/C2CC32036C

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