Evidence for magnetic anisotropy of [NbIV(CN)8]4− in a pillared-layered Mn2Nb framework showing spin-flop transition†
Abstract
The first example of the [Nb(CN)8]-based pillared-layered-type framework system {[MnII2(bpdo)(H2O)4][NbIV(CN)8]·6H2O}n (bpdo =