Issue 47, 2012
From the journal:

Chemical Communications

An inorganic propellane with central B–B bond†‡

Steffen Pospiech,a   Sarah Brough,b   Michael Bolte,a   Hans-Wolfram Lerner,a   Holger F. Bettingerb  and  Matthias Wagner*a  

* Corresponding authors

a Institut für Anorganische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, D-60438 Frankfurt (Main), Germany
E-mail: Matthias.Wagner@chemie.uni-frankfurt.de
Fax: +49 69 798 29260

b Institut für Organische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany
E-mail: Holger.Bettinger@uni-tuebingen.de
Fax: +49 7071 29 5244

Abstract

9,10-Dihydroanthracene-9,10-diyl-bridged B2(NMe2)2 readily adds [H2NMe2]+, HCl and F3CCOOH across its partial B[double bond, length as m-dash]N double bond(s), thereby forming mono- or diadducts; treatment with 1-iso-propyl-2-mercaptoimidazole leads to a triply B–B-bridged propellane-like structure.

Graphical abstract: An inorganic propellane with central B–B bond

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Article information

DOI
https://doi.org/10.1039/C2CC32256K
Article type
Communication
Submitted
28 Mar 2012
Accepted
23 Apr 2012
First published
24 Apr 2012

Chem. Commun., 2012,48, 5886-5888

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An inorganic propellane with central B–B bond

S. Pospiech, S. Brough, M. Bolte, H. Lerner, H. F. Bettinger and M. Wagner, Chem. Commun., 2012, 48, 5886 DOI: 10.1039/C2CC32256K

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