Issue 48, 2012
From the journal:

Chemical Communications

Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster†

Jiangtao Jia,a   Fuxing Sun,a   Tsolmon Borjigin,a   Hao Ren,a   Tingting Zhang,a   Zheng Bian,*b   Lianxun Gaob  and  Guangshan Zhu*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: zhugs@jlu.edu.cn
Fax: +86-431-85168331
Tel: +86-431-85168887

b State Key laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
E-mail: bianzh@ciac.jl.cn
Fax: +86-431-85697831
Tel: +86-431-85262291

Abstract

Two non-interpenetrated and isomorphous MOFs with nia topology, cationic JUC-101 and anionic JUC-102, are synthesized by connecting a trigonal prismatic metal cluster with an octahedral organic ligand. JUC-101 obtains a BET surface area of 3742 m2 gāˆ’1 and can absorb 4.18 wt% of H2 at 30 atm and 77 K, while JUC-102 can absorb cationic dye molecules and release them under the triggering of ions.

Graphical abstract: Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

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Article information

DOI
https://doi.org/10.1039/C2CC32347H
Article type
Communication
Submitted
01 Apr 2012
Accepted
27 Apr 2012
First published
27 Apr 2012

Chem. Commun., 2012,48, 6010-6012

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Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

J. Jia, F. Sun, T. Borjigin, H. Ren, T. Zhang, Z. Bian, L. Gao and G. Zhu, Chem. Commun., 2012, 48, 6010 DOI: 10.1039/C2CC32347H

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