Designed cyanide- and phenoxide-bridged FeIIIMnIII single-molecule magnet constructed by highly blocked paramagnetic precursors

Kyung Jin Cho; Dae Won Ryu; Hyun Young Kwak; Jin Wuk Lee; Woo Ram Lee; Kwang Soo Lim; Eui Kwan Koh; Young Wan Kwon; Chang Seop Hong

doi:10.1039/C2CC32503A

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Designed cyanide- and phenoxide-bridged Fe^IIIMn^III single-molecule magnet constructed by highly blocked paramagnetic precursors†

Kyung Jin Cho,‡^a Dae Won Ryu,‡^a Hyun Young Kwak,^a Jin Wuk Lee,^a Woo Ram Lee,^a Kwang Soo Lim,^a Eui Kwan Koh,^b Young Wan Kwon^a and Chang Seop Hong*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea
E-mail: cshong@korea.ac.kr

^b Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

Abstract

A tetranuclear Fe^III₂Mn^III₂ compound was prepared using highly blocked precursors. The well-isolated molecular entity associated with appropriate magnetic anisotropy allows for single-molecule magnet behavior.

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Article information

DOI: https://doi.org/10.1039/C2CC32503A
Article type: Communication
Submitted: 07 Apr 2012
Accepted: 01 Jun 2012
First published: 08 Jun 2012

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Chem. Commun., 2012,48, 7404-7406

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Designed cyanide- and phenoxide-bridged Fe^IIIMn^III single-molecule magnet constructed by highly blocked paramagnetic precursors

K. J. Cho, D. W. Ryu, H. Y. Kwak, J. W. Lee, W. R. Lee, K. S. Lim, E. K. Koh, Y. W. Kwon and C. S. Hong, Chem. Commun., 2012, 48, 7404 DOI: 10.1039/C2CC32503A

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