Issue 53, 2012
From the journal:

Chemical Communications

On the Diels–Alder dimerisation of cross-conjugated trienes†

Henry Toombs-Ruane,a   Emma L. Pearson,a   Michael N. Paddon-Row*b  and  Michael S. Sherburn*a  

* Corresponding authors

a Australian Research Council Centre of Excellence for Free Radical Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, Australia
E-mail: sherburn@rsc.anu.edu.au (synthetic)

b School of Chemistry, The University of New South Wales, Sydney, Australia
E-mail: m.paddonrow@unsw.edu.au (computational)

Abstract

The first general synthesis of 1-substituted [3]dendralenes has led to the discovery that conjugating groups significantly enhance the rate of Diels–Alder dimerisation relative to both the parent [3]dendralene and to other substituted systems.

Graphical abstract: On the Diels–Alder dimerisation of cross-conjugated trienes

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Article information

DOI
https://doi.org/10.1039/C2CC32520A
Article type
Communication
Submitted
08 Apr 2012
Accepted
08 May 2012
First published
09 May 2012

Chem. Commun., 2012,48, 6639-6641

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On the Diels–Alder dimerisation of cross-conjugated trienes

H. Toombs-Ruane, E. L. Pearson, M. N. Paddon-Row and M. S. Sherburn, Chem. Commun., 2012, 48, 6639 DOI: 10.1039/C2CC32520A

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