Issue 54, 2012
From the journal:

Chemical Communications

Multielectron reduction of diazoalkane and azidesvia reversible cyclometalation in ditantalum complexes†

Takashi Kurogi,a   Yutaka Ishida,a   Tsubasa Hatanakaa  and  Hiroyuki Kawaguchi*a  

* Corresponding authors

a Department of Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551, Japan
E-mail: hkawa@chem.titech.ac.jp

Abstract

Reactions of the cyclometalated hydride complexes with diazo and azide substrates are reported. While diazoalkane undergoes four-electron N–N bond cleavage, azides undergo two-electron N2 extrusion.

Graphical abstract: Multielectron reduction of diazoalkane and azides via reversible cyclometalation in ditantalum complexes

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Article information

DOI
https://doi.org/10.1039/C2CC32535G
Article type
Communication
Submitted
09 Apr 2012
Accepted
15 May 2012
First published
16 May 2012

Chem. Commun., 2012,48, 6809-6811

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Multielectron reduction of diazoalkane and azides via reversible cyclometalation in ditantalum complexes

T. Kurogi, Y. Ishida, T. Hatanaka and H. Kawaguchi, Chem. Commun., 2012, 48, 6809 DOI: 10.1039/C2CC32535G

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