Issue 53, 2012
From the journal:

Chemical Communications

The influence of non-covalent interactions on the hydrogen peroxide electrochemistry on platinum in alkaline electrolytes†

Ioannis Katsounaros*a  and  Karl J. J. Mayrhofer*a  

* Corresponding authors

a Department of Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1, 40237 Düsseldorf, Germany
E-mail: katsounaros@mpie.de, mayrhofer@mpie.de
Fax: +49 211 6792 218
Tel: +49 211 6792 160

Abstract

The potential range of the transition region between the diffusion-limited reduction to oxidation of hydrogen peroxide depends strongly on the nature of the cation of the supporting alkaline electrolyte. Non-covalent interactions between the hydrated alkali metal cations and chemisorbed OH species on platinum influence the potential-dependent reaction kinetics.

Graphical abstract: The influence of non-covalent interactions on the hydrogen peroxide electrochemistry on platinum in alkaline electrolytes

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Article information

DOI
https://doi.org/10.1039/C2CC32652C
Article type
Communication
Submitted
14 Apr 2012
Accepted
14 May 2012
First published
14 May 2012

Chem. Commun., 2012,48, 6660-6662

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The influence of non-covalent interactions on the hydrogen peroxide electrochemistry on platinum in alkaline electrolytes

I. Katsounaros and K. J. J. Mayrhofer, Chem. Commun., 2012, 48, 6660 DOI: 10.1039/C2CC32652C

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