Issue 62, 2012
From the journal:

Chemical Communications

Highly stereoselective Ru(ii)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate†

Soda Chanthamath,a   Kesiny Phomkeona,a   Kazutaka Shibatomia  and  Seiji Iwasa*a  

* Corresponding authors

a Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Japan
E-mail: iwasa@ens.tut.ac.jp
Fax: +81-523-44-6817
Tel: +81-532-44-6817

Abstract

The Ru(II)–Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereoselectivity and enantioselectivity.

Graphical abstract: Highly stereoselective Ru(ii)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

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Article information

DOI
https://doi.org/10.1039/C2CC32706F
Article type
Communication
Submitted
17 Apr 2012
Accepted
08 Jun 2012
First published
12 Jun 2012

Chem. Commun., 2012,48, 7750-7752

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Highly stereoselective Ru(II)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

S. Chanthamath, K. Phomkeona, K. Shibatomi and S. Iwasa, Chem. Commun., 2012, 48, 7750 DOI: 10.1039/C2CC32706F

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