Issue 57, 2012
From the journal:

Chemical Communications

Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene†

Celedonio M. Álvarez,a   Luis A. García-Escudero,a   Raúl García-Rodrígueza  and  Daniel Miguel*a  

* Corresponding authors

a GIR-MIOMeT-IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena, s/n 47005, Valladolid, Spain
E-mail: dmsj@qi.uva.es
Fax: +34 983423013
Tel: +34 983184096

Abstract

The exceptional versatility of the 1,2,3-triazole ring in tridentate carbonyl rhenium complexes has been explored starting from a “click chemistry” unexpected product obtained from the spontaneous copper to rhenium transmetalation, which opens the way to successive transformation to C-triazolyl and triazolylidene mesoionic carbene.

Graphical abstract: Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC32725B
Article type
Communication
Submitted
17 Apr 2012
Accepted
28 May 2012
First published
29 May 2012

Chem. Commun., 2012,48, 7209-7211

Permissions

Request permissions

Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

C. M. Álvarez, L. A. García-Escudero, R. García-Rodríguez and D. Miguel, Chem. Commun., 2012, 48, 7209 DOI: 10.1039/C2CC32725B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements