Issue 55, 2012
From the journal:

Chemical Communications

Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds†

Yoshihiro Miyake,a   Yuya Ashida,a   Kazunari Nakajimaa  and  Yoshiaki Nishibayashi*a  

* Corresponding authors

a Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, Japan
E-mail: ynishiba@sogo.t.u-tokyo.ac.jp
Fax: +81 3-5841-1175
Tel: +81 3-5841-1175

Abstract

Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds using a photoredox catalyst is developed. We also succeeded in the isolation of a silyl enol ether as a primary product of the photochemical reaction.

Graphical abstract: Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/C2CC32745G
Article type
Communication
Submitted
18 Apr 2012
Accepted
16 May 2012
First published
17 May 2012

Chem. Commun., 2012,48, 6966-6968

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Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

Y. Miyake, Y. Ashida, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2012, 48, 6966 DOI: 10.1039/C2CC32745G

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