Issue 67, 2012
From the journal:

Chemical Communications

Stabilisation of a triply-bridging cyclopentadienylligand in a tetrapalladium cluster†‡

Kirill Yu. Monakhov,a   Christophe Gourlaouenb  and  Pierre Braunstein*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, F-67081 Strasbourg, France
E-mail: braunstein@unistra.fr

b Laboratoire de Chimie Quantique, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 1 rue Blaise Pascal, F-67008 Strasbourg, France

Abstract

An unusual triply-bridging cyclopentadienyl (C5H5 = Cp) ligand has been characterised in the tetranuclear palladium cluster [Pd3II(μ-OAc)4(μ3-Cp)Pd0(η5-Cp)] (1). It is coordinated in the μ3-η1:η2:η2 mode to a [Pd3]4+ triangular subunit of the mixed-valence cluster 1.

Graphical abstract: Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster

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Article information

DOI
https://doi.org/10.1039/C2CC32886K
Article type
Communication
Submitted
23 Apr 2012
Accepted
10 Jun 2012
First published
12 Jun 2012

Chem. Commun., 2012,48, 8317-8319

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Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster

K. Yu. Monakhov, C. Gourlaouen and P. Braunstein, Chem. Commun., 2012, 48, 8317 DOI: 10.1039/C2CC32886K

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