Issue 63, 2012
From the journal:

Chemical Communications

Ferrocenophanes with gallium and silicon as alternating bridges†

Bidraha Bagh,a   Nora C. Breit,a   Joe B. Gilroy,b   Gabriele Schattec  and  Jens Müller*a  

* Corresponding authors

a Department of Chemistry, University of Saskatchewan, 110 Science Place, Saskatchewan S7N 5C9, Saskatoon, Canada
E-mail: jens.mueller@usask.ca
Fax: (+)306 966 4730
Tel: (+)306 966 2466

b School of Chemistry, University of Bristol, Bristol BS8 1TS, UK

c Saskatchewan Structural Sciences Centre, University of Saskatchewan, 110 Science Place, Saskatchewan S7N 5C9, Saskatoon, Canada

Abstract

[1.1]Ferrocenophanes with gallium and silicon in bridging positions have been prepared in yields of 29 and 41%, respectively. From the same reactions, polymer-containing fractions were isolated (31% in each case) and shown to be comprised of linear and cyclic species with up to 16 ferrocene units (MALDI-TOF analysis).

Graphical abstract: Ferrocenophanes with gallium and silicon as alternating bridges

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Article information

DOI
https://doi.org/10.1039/C2CC32967K
Article type
Communication
Submitted
25 Apr 2012
Accepted
07 Jun 2012
First published
11 Jun 2012

Chem. Commun., 2012,48, 7823-7825

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Ferrocenophanes with gallium and silicon as alternating bridges

B. Bagh, N. C. Breit, J. B. Gilroy, G. Schatte and J. Müller, Chem. Commun., 2012, 48, 7823 DOI: 10.1039/C2CC32967K

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