Issue 65, 2012
From the journal:

Chemical Communications

Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system†

Wei-Ning Cao,a   Feng Wang,a   Hong-Yan Wang,a   Bin Chen,a   Ke Feng,a   Chen-Ho Tunga  and  Li-Zhu Wu*a  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & Graduate University, The Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: lzwu@mail.ipc.ac.cn

Abstract

Combined with a simple water soluble [FeFe]-hydrogenase mimic 1, Ru(bpy)32+ and ascorbic acid enable hydrogen production photocatalytically. More than 88 equivalents of H2 were achieved in water, which is much better than that obtained in an organic solvent or a mixture of organic solvent and water.

Graphical abstract: Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system

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Article information

DOI
https://doi.org/10.1039/C2CC33097K
Article type
Communication
Submitted
29 Apr 2012
Accepted
26 Jun 2012
First published
26 Jun 2012

Chem. Commun., 2012,48, 8081-8083

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Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system

W. Cao, F. Wang, H. Wang, B. Chen, K. Feng, C. Tung and L. Wu, Chem. Commun., 2012, 48, 8081 DOI: 10.1039/C2CC33097K

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