Copper-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via radical mechanism

Hailong Yang; Peng Sun; Yan Zhu; Hong Yan; Linhua Lu; Xiaoming Qu; Tingyi Li; Jincheng Mao

doi:10.1039/C2CC33203E

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Copper-catalyzed decarboxylative C(sp²)–C(sp³) coupling reactions via radical mechanism†

Hailong Yang,^a Peng Sun,^a Yan Zhu,^a Hong Yan,^a Linhua Lu,^a Xiaoming Qu,^a Tingyi Li^a and Jincheng Mao*^a

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* Corresponding authors

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China
E-mail: jcmao@suda.edu.cn

Abstract

We have successfully developed an example of copper-catalyzed decarboxylative C(sp²)–C(sp³) coupling reactions via C–H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.

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Article information

DOI: https://doi.org/10.1039/C2CC33203E
Article type: Communication
Submitted: 04 May 2012
Accepted: 18 Jun 2012
First published: 19 Jun 2012

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Chem. Commun., 2012,48, 7847-7849

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Copper-catalyzed decarboxylative C(sp²)–C(sp³) coupling reactions via radical mechanism

H. Yang, P. Sun, Y. Zhu, H. Yan, L. Lu, X. Qu, T. Li and J. Mao, Chem. Commun., 2012, 48, 7847 DOI: 10.1039/C2CC33203E

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