Issue 66, 2012

Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels

Abstract

Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.

Graphical abstract: Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels

Supplementary files

Article information

Article type
Communication
Submitted
22 May 2012
Accepted
25 Jun 2012
First published
28 Jun 2012

Chem. Commun., 2012,48, 8207-8209

Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels

J. Martí-Rujas, L. Colombo, J. Lü, A. Dey, G. Terraneo, P. Metrangolo, T. Pilati and G. Resnati, Chem. Commun., 2012, 48, 8207 DOI: 10.1039/C2CC33682K

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