A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.
C. Gao, X. He, L. Zhao and M. Wang, Chem. Commun., 2012, 48, 8368 DOI: 10.1039/C2CC33757F
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