Issue 67, 2012
From the journal:

Chemical Communications

A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units†

Stefan Spirk,a   Ferdinand Belaj,a   Natascha Hurkesab  and  Rudolf Pietschnig*ab  

* Corresponding authors

a Institute of Chemistry, University of Graz, Schubertstr. 1, 8010 Graz, Austria

b Institute of Chemistry and Center for Interdisciplinary Nanostructure Science and Technology, University of Kassel, Heinrich-Plett-Strasse 40, 34132 Kassel, Germany
E-mail: pietschnig@uni-kassel.de
Fax: +49 561 804 4649
Tel: +49 561 804 4458

Abstract

A high yield synthesis of the first silanedithiolate silanolate is reported which spontaneously assembles forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by sterically demanding 2,6-dimesitylphenyl substituents and two LiCl units.

Graphical abstract: A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units

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Article information

DOI
https://doi.org/10.1039/C2CC33883A
Article type
Communication
Submitted
30 May 2012
Accepted
28 Jun 2012
First published
29 Jun 2012

Chem. Commun., 2012,48, 8398-8400

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A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units

S. Spirk, F. Belaj, N. Hurkes and R. Pietschnig, Chem. Commun., 2012, 48, 8398 DOI: 10.1039/C2CC33883A

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