Highly conductive free standing polypyrrole (PPy) films were prepared by a novel freezing interfacial polymerization method. The films exhibit metallic luster and electrical conductivity up to 2000 S cm−1. By characterizing with SEM, FTIR, Raman and XRD, the high conductivity is attributed to the smooth surface, higher conjugation length and more ordered molecular structure of PPy.
G. Qi, L. Huang and H. Wang, Chem. Commun., 2012, 48, 8246 DOI: 10.1039/C2CC33889K
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