Issue 64, 2012
From the journal:

Chemical Communications

Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide†

Tetsuaki Fujihara,a   Tomoya Hosoki,a   Yuko Katafuchi,a   Tomohiro Iwai,a   Jun Teraoa  and  Yasushi Tsuji*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
E-mail: ytsuji@scl.kyoto-u.ac.jp
Fax: +81-75-383-2514
Tel: +81-75-383-2515

Abstract

Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.

Graphical abstract: Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

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Article information

DOI
https://doi.org/10.1039/C2CC33944G
Article type
Communication
Submitted
01 Jun 2012
Accepted
22 Jun 2012
First published
22 Jun 2012

Chem. Commun., 2012,48, 8012-8014

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Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

T. Fujihara, T. Hosoki, Y. Katafuchi, T. Iwai, J. Terao and Y. Tsuji, Chem. Commun., 2012, 48, 8012 DOI: 10.1039/C2CC33944G

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