Issue 67, 2012

Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

Abstract

We report here the regioselective synthesis of aryl chalcogenides through the iridium-catalyzed meta C–H borylation followed by copper-catalyzed C–S coupling reaction with chalcogenide sources in one pot, giving the 3,5-disubstituted aryl chalcogenides with high regioselectivity and good yields.

Graphical abstract: Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2012
Accepted
03 Jul 2012
First published
04 Jul 2012

Chem. Commun., 2012,48, 8440-8442

Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

J. Cheng, C. Yi, T. Liu and C. Lee, Chem. Commun., 2012, 48, 8440 DOI: 10.1039/C2CC33950A

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