Issue 72, 2012
From the journal:

Chemical Communications

Porous vanadium-doped titania with active hydrogen: a renewable reductant for chemoselective hydrogenation of nitroarenes under ambient conditions†

Juan Su,ab   Xiao-Xin Zou,ab   Guo-Dong Li,b   Lu Li,ab   Jun Zhaob  and  Jie-Sheng Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: chemcj@sjtu.edu.cn
Fax: +86-21-54741297
Tel: +86-21-54743266

b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Abstract

A vanadium-doped porous titania rich in active hydrogen (V–TiO2(H*)) has been successfully prepared and demonstrated to be an efficient and green reductant with renewable capacity. This V–TiO2(H*) material can instantly (<10 s) and selectively reduce nitroarenes to aminoarenes under ambient conditions without catalysts.

Graphical abstract: Porous vanadium-doped titania with active hydrogen: a renewable reductant for chemoselective hydrogenation of nitroarenes under ambient conditions

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Article information

DOI
https://doi.org/10.1039/C2CC33969B
Article type
Communication
Submitted
03 Jun 2012
Accepted
14 Jul 2012
First published
18 Jul 2012

Chem. Commun., 2012,48, 9032-9034

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Porous vanadium-doped titania with active hydrogen: a renewable reductant for chemoselective hydrogenation of nitroarenes under ambient conditions

J. Su, X. Zou, G. Li, L. Li, J. Zhao and J. Chen, Chem. Commun., 2012, 48, 9032 DOI: 10.1039/C2CC33969B

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