Issue 67, 2012
From the journal:

Chemical Communications

Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide†

Cédric Boyère,a   Alexandre F. Léonard,b   Bruno Grignard,a   Audrey Favrelle,a   Jean-Paul Pirard,b   Michel Paquot,c   Christine Jérômea  and  Antoine Debuigne*a  

* Corresponding authors

a Center for Education and Research on Macromolecules (CERM), Chemistry Department, University of Liege, Sart-Tilman, Allée de la Chimie 3, Bat B6a, B-4000 Liege, Belgium
E-mail: adebuigne@ulg.ac.be
Fax: +32 4 366 34 97
Tel: +32 4 366 35 65

b Laboratory of Chemical Engineering, University of Liege, Sart-Tilman, Allée de la Chimie 3, Bat B6a, B-4000 Liege, Belgium

c Unit of Biological and Industrial Chemistry, University of Liege, Gembloux Agro-Bio Tech, Passage des Déportés 2, B-5030 Gembloux, Belgium

Abstract

Highly porous materials were produced by acrylamide polymerisation templated by supercritical CO2-in-water emulsions using new fluorinated glycosurfactants. Properties of the resulting polymer scaffolds were tuned by performing dispersion polymerisations within their cavities filled with supercritical CO2.

Graphical abstract: Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/C2CC33978A
Article type
Communication
Submitted
27 Apr 2012
Accepted
29 Jun 2012
First published
29 Jun 2012

Chem. Commun., 2012,48, 8356-8358

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Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide

C. Boyère, A. F. Léonard, B. Grignard, A. Favrelle, J. Pirard, M. Paquot, C. Jérôme and A. Debuigne, Chem. Commun., 2012, 48, 8356 DOI: 10.1039/C2CC33978A

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