Issue 77, 2012
From the journal:

Chemical Communications

Poly(polyoxometalate)s assembled by {Ni6PW9} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers†

Ling Huang,a   Jie Zhang,a   Lin Chenga  and  Guo-Yu Yang*ab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: ygy@fjirsm.ac.cn
Fax: +86 591-8371-0051

b DOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Abstract

Both structure-directing effect and synergistic-directing effect of PW9O34 fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni24-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni40-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

Graphical abstract: Poly(polyoxometalate)s assembled by {Ni6PW9} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers

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Article information

DOI
https://doi.org/10.1039/C2CC34332K
Article type
Communication
Submitted
17 Jun 2012
Accepted
10 Aug 2012
First published
13 Aug 2012

Chem. Commun., 2012,48, 9658-9660

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Poly(polyoxometalate)s assembled by {Ni6PW9} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers

L. Huang, J. Zhang, L. Cheng and G. Yang, Chem. Commun., 2012, 48, 9658 DOI: 10.1039/C2CC34332K

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