Issue 85, 2012
From the journal:

Chemical Communications

Pd-catalyzed borylative cyclisation of 1,7-enynes†‡

Virtudes Pardo-Rodríguez,a   Elena Buñuel,a   Daniel Collado-Sanza  and  Diego J. Cárdenas*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain
E-mail: diego.cardenas@uam.es
Fax: +34 914973966
Tel: +34 914974358

Abstract

Reaction of a variety of 1,7-enynes with bis(pinacolato) diboron catalysed by Pd bis(trifluoroacetate) affords homoallylic and allylic boronates containing a six membered carbo- or heterocycle, by formation of C–C and C–B bonds

Graphical abstract: Pd-catalyzed borylative cyclisation of 1,7-enynes

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Article information

DOI
https://doi.org/10.1039/C2CC34468H
Article type
Communication
Submitted
21 Jun 2012
Accepted
16 Aug 2012
First published
24 Aug 2012

Chem. Commun., 2012,48, 10517-10519

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Pd-catalyzed borylative cyclisation of 1,7-enynes

V. Pardo-Rodríguez, E. Buñuel, D. Collado-Sanz and D. J. Cárdenas, Chem. Commun., 2012, 48, 10517 DOI: 10.1039/C2CC34468H

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