Issue 68, 2012
From the journal:

Chemical Communications

Generation of 3-(1H-pyrrol-3-yl)-1H-inden-1-ones via a tandem reaction of 1-(2-alkynylphenyl)-2-enone, 2-isocyanoacetate, and water†

Danqing Zheng,a   Shaoyu Lia  and  Jie Wu*ab  

* Corresponding authors

a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China
E-mail: jie_wu@fudan.edu.cn
Fax: +86 21 6564 1740
Tel: +86 21 6510 2412

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China

Abstract

A silver triflate-catalyzed tandem reaction of 1-(2-alkynylphenyl)-2-enone, 2-isocyanoacetate, and water provides a novel and efficient route for the delivery of 3-(1H-pyrrol-3-yl)-1H-inden-1-ones. Four bonds are formed during the tandem process.

Graphical abstract: Generation of 3-(1H-pyrrol-3-yl)-1H-inden-1-ones via a tandem reaction of 1-(2-alkynylphenyl)-2-enone, 2-isocyanoacetate, and water

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Article information

DOI
https://doi.org/10.1039/C2CC34509A
Article type
Communication
Submitted
04 May 2012
Accepted
04 Jul 2012
First published
04 Jul 2012

Chem. Commun., 2012,48, 8568-8570

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Generation of 3-(1H-pyrrol-3-yl)-1H-inden-1-ones via a tandem reaction of 1-(2-alkynylphenyl)-2-enone, 2-isocyanoacetate, and water

D. Zheng, S. Li and J. Wu, Chem. Commun., 2012, 48, 8568 DOI: 10.1039/C2CC34509A

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