Issue 70, 2012
From the journal:

Chemical Communications

Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments†

Mirco Natali,a   Serena Berardi,b   Andrea Sartorel,*b   Marcella Bonchio,b   Sebastiano Campagnac  and  Franco Scandola*a  

* Corresponding authors

a Dipartimento di Chimica, Università di Ferrara, and Centro Interuniversitario per la Conversione Chimica dell'Energia Solare, sez. di Ferrara, Via L. Borsari 46, 44121 Ferrara, Italy
E-mail: snf@unife.it

b ITM-CNR and Dipartimento di Scienze Chimiche, Università di Padova, Via F. Marzolo 1, 35131 Padova, Italy
E-mail: andrea.sartorel@unipd.it

c Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina and Centro Interuniversitario per la Conversione Chimica dell'Energia Solare, sezione di Messina, Via Sperone 31, 98166 Messina, Italy
E-mail: campagna@unime.it

Abstract

Water oxidation catalysts: evolution of [Co4(H2O)2(α-PW9O34)2]10− to catalytically active species is assessed by laser flash photolysis in sacrificial photocatalytic cycles with Ru(bpy)32+ as a photosensitizer.

Graphical abstract: Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

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Article information

DOI
https://doi.org/10.1039/C2CC34804G
Article type
Communication
Submitted
05 Jul 2012
Accepted
16 Jul 2012
First published
26 Jul 2012

Chem. Commun., 2012,48, 8808-8810

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Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

M. Natali, S. Berardi, A. Sartorel, M. Bonchio, S. Campagna and F. Scandola, Chem. Commun., 2012, 48, 8808 DOI: 10.1039/C2CC34804G

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