Issue 85, 2012
From the journal:

Chemical Communications

Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers†

Shingo Ito,*a   Masaki Noguchia  and  Kyoko Nozaki*a  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: ito_shingo@chembio.t.u-tokyo.ac.jp, nozaki@chembio.t.u-tokyo.ac.jp
Fax: +81 3-5841-7263
Tel: +81 3-5841-7261

Abstract

Inspired by the enzymatic ping-pong mechanism, we designed a novel “ping-pong polymerization”, which employs allylation and hydroformylation in an iterative and alternating manner. Thus, alternating and regioregular vinyl alcohol–vinyl monomer copolymers possessing multiple hydroxy groups in a periodical manner were successfully synthesized.

Graphical abstract: Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers

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Article information

DOI
https://doi.org/10.1039/C2CC34980A
Article type
Communication
Submitted
12 Jul 2012
Accepted
23 Aug 2012
First published
24 Aug 2012

Chem. Commun., 2012,48, 10481-10483

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Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers

S. Ito, M. Noguchi and K. Nozaki, Chem. Commun., 2012, 48, 10481 DOI: 10.1039/C2CC34980A

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